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This paragraph applies to all operations involving the immersion of materials in liquids, or in the vapors of such liquids, for the purpose of cleaning or altering the surface or adding to or imparting a finish thereto or changing the character of the materials, and their subsequent removal from the liquid or vapor, draining, and drying. These operating include washing, electroplating, anodizing, pickling, quenching, dying, dipping, tanning, dressing, bleaching, degreasing, alkaline cleaning, stripping, rinsing, digesting, and other similar operation.
Except where specific construction specifications are prescribed in this section, hoods, ducts, elbows, fans, blowers, and all other exhaust system parts, components, and supports thereof shall be so constructed as to meet conditions of service and to facilitate maintenance and shall conform in construction to the specifications contained in American National Standard Fundamentals Governing the Design and Operation of Local Exhaust Systems, Z9.2-1960.
Open-surface tank operations shall be classified into 16 classes, numbered A-1 to D-4, inclusive.
Hazard potential is an index, on a scale of from A to D, inclusive, of the severity of the hazard associated with the substance contained in the tank because of the toxic, flammable, or explosive nature of the vapor, gas, or mist produced there from. The toxic hazard is determined from the concentration, measured in parts by volume of a gas or vapor, per million parts by volume of contaminated air (p.p.m.), or in milligrams of mist per cubic meter of air (mg./m(3)), below which ill effects are unlikely to occur to the exposed worker. The concentrations shall be those in 1926.55 or other pertinent sections of this part.
The relative fire or explosion hazard is measured in degrees Fahrenheit in terms of the closed-cup flash point of the substance in the tank. Detailed information on the prevention of fire hazards in dip tanks may be found in Dip Tanks Containing Flammable or Combustible Liquids, NFPA No. 34-1966, National Fire Protection Association. Where the tank contains a mixture of liquids, other than organic solvents, whose effects are additive, the hygienic standard of the most toxic component (for example, the one having the lowest p.p.m. or mg/m(3)) shall be used, except where such substance constitutes an insignificantly small faction of the mixture. For mixtures of organic solvents, their combined effect, rather than that of either individually, shall determine the hazard potential. In the absence of information to the contrary, the effects shall be considered as additive. If the sum of the ratios of the airborne concentration of each contaminant to the toxic concentration of that contaminant exceeds unity, the toxic concentration shall be considered to have been exceeded. (See Note A to paragraph (i)(2)(v) of this section.)
Hazard potential shall be determined from Table D-57.9, with the value indicating greater hazard being used. When the hazardous material may be either a vapor with a threshold limit value (TLV) in p.p.m. or a mist with a TLV in mg/m(3), the TLV indicating the greater hazard shall be used (for example, A takes precedence over B or C; B over C; C over D).
Note A:
where:
c = Concentration measured at the operation in p.p.m.
Note A:
(c1 ÷ TLV1) ÷ (c2 ÷ TLV2)+(c3 ÷ TLV3;... (cN ÷ TLVN)1
where:
c = Concentration measured at the operation in p.p.m.
TABLE D-57.9 - DETERMINATION OF HAZARD POTENTIAL
| Hazard potential | Toxicity group | ||
| Gas or vapor (p.p.m.) |
Mist (mg./m3 |
Flash point in degrees F. (C.) |
|
| A | 0-10 | 0-0.1 | |
| B | 11-100 | 0.11-1.0 | Under 100 (37.77) |
| C | 101-500 | 1.1-10 | 100,200 (37.77-93.33) |
| D | Over 500 | Over 10 | Over 200 (93.33) |
Rate of gas, vapor, or mist evolution is a numerical index, on a scale of from 1 to 4, inclusive, both of the relative capacity of the tank to produce gas, vapor, or mist and of the relative energy with which it is projected or carried upwards from the tank. Rate is evaluated in terms of
The temperature of the liquid in the tank in degrees Fahrenheit;
The number of degrees Fahrenheit that this temperature is below the boiling point of the liquid in degrees Fahrenheit;
The relative evaporation of the liquid in still air at room temperature in an arbitrary scale -- fast, medium, slow, or nil; and
The extent that the tank gases or produces mist in an arbitrary scale -- high, medium, low, and nil. (See Table D-57.10, Note 2.) Gassing depends upon electrochemical or mechanical processes, the effects of which have to be individually evaluated for each installation (see Table D-57.10, Note 3).
Rate of evolution shall be determined from Table D-57.10. When evaporation and gassing yield different rates, the lowest numerical value shall be used.
Footnote(1) In certain classes of equipment, specifically vapor degreasers, an internal condenser or vapor level thermostat is used to prevent the vapor from leaving the tank during normal operation. In such cases, rate of vapor evolution from the tank into the workroom is not dependent upon the factors listed in the table, but rather upon abnormalities of operating procedure, such as carryout of vapors from excessively fast action, dragout of liquid by entrainment in parts, contamination of solvent by water and other materials, or improper heat balance. When operating procedure is excellent, effective rate of evolution may be taken as 4. When operating procedure is average, the effective rate of evolution may be taken as 3.
Footnote(2) Relative evaporation rate is determined according to the methods described by A. K. Doolittle in Industrial and Engineering Chemistry, vol. 27 p. 1169, (3) where time for 100-percent evaporation is as follows: Fast: 0-3 hours; Medium: 3-12 hours; Slow: 12-50 hours; Nil: more than 50 hours.
Footnote(3) Gassing means the formation by chemical or electrochemical action of minute bubbles of gas under the surface of the liquid in the tank and is generally limited to aqueous solutions.
| Rate | Liquid temperature, deg. F (C) |
Degrees below boiling point |
Relative evaporation(2) |
Gassing(3) |
| 1 | Over 200 (93.33) | 0-20 | Fast | High. |
| 2 | 150-200 (65.55-93.33) | 21-50 | Medium | Medium |
| 3 | 94-149 (34.44-65) | 51-100 | Slow | Low. |
| 4 | Under 94 (34.44) | Over 100 | Nil | Nil. |
Footnote(1) In certain classes of equipment, specifically vapor degreasers, an internal condenser or vapor level thermostat is used to prevent the vapor from leaving the tank during normal operation. In such cases, rate of vapor evolution from the tank into the workroom is not dependent upon the factors listed in the table, but rather upon abnormalities of operating procedure, such as carryout of vapors from excessively fast action, dragout of liquid by entrainment in parts, contamination of solvent by water and other materials, or improper heat balance. When operating procedure is excellent, effective rate of evolution may be taken as 4. When operating procedure is average, the effective rate of evolution may be taken as 3.
Footnote(2) Relative evaporation rate is determined according to the methods described by A. K. Doolittle in Industrial and Engineering Chemistry, vol. 27 p. 1169, (3) where time for 100-percent evaporation is as follows: Fast: 0-3 hours; Medium: 3-12 hours; Slow: 12-50 hours; Nil: more than 50 hours.
Footnote(3) Gassing means the formation by chemical or electrochemical action of minute bubbles of gas under the surface of the liquid in the tank and is generally limited to aqueous solutions.
Class is determined by two factors, hazard potential designated by a letter from A to D, inclusive, and rate of gas, vapor, or mist evolution designated by a number from 1 to 4, inclusive (for example, B.3).
Where ventilation is used to control potential exposures to workers as defined in paragraph (i)(2)(iii) of this section, it shall be adequate to reduce the concentration of the air contaminant to the degree that a hazard to the worker does not exist. Methods of ventilation are discussed in American National Standard Fundamentals Governing the Design and Operation of Local Exhaust Systems, Z9.2-1960.
Control velocities shall conform to Table D-57.11 in all cases where the flow of air past the breathing or working zone of the operator and into the hoods is undisturbed by local environmental conditions, such as open windows, wall fans, unit heaters, or moving machinery.
All tanks exhausted by means of hoods which do not project over the entire tank, and in which the direction of air movement into the hood or hoods is substantially horizontal, shall be considered to be laterally exhausted. The quantity of air in cubic feet per minute necessary to be laterally exhausted per square foot of tank area in order to maintain the required control velocity shall be determined from Table D-57.12 for all variations in ratio of tank width (W) to tank length (L). The total quantity of air in cubic feet per minute required to be exhausted per tank shall be not less than the product of the area of tank surface times the cubic feet per minute per square foot of tank area, determined from Table D-57.12.
For lateral exhaust hoods over 42 inches (1.06 m) wide, or where it is desirable to reduce the amount of air removed from the workroom, air supply slots or orifices shall be provided along the side or the center of the tank opposite from the exhaust slots. The design of such systems shall meet the following criteria:
The supply air volume plus the entrained air shall not exceed 50 percent of the exhaust volume.
The velocity of the supply airstream as it reaches the effective control area of the exhaust slot shall be less than the effective velocity over the exhaust slot area.
Footnote(1) It is not practicable to ventilate across the long
dimension of a tank whose ratio W/L exceeds 2.0.
It is undesirable to do so when W/L exceeds 1.0. For circular tanks
with lateral exhaust along up to 1/2 the circumference, use W/L=1.0; for over one-half the circumference use W/L=0.5.
Footnote(2) Baffle is a vertical plate the same length as the tank,
and with the top of the plate as high as the tank is wide. If the exhaust hood is on the side of a tank against a building wall or close to it, it is perfectly baffled.
Footnote(3) Use W/2 as tank width in computing when manifold is along centerline, or when hoods are used on two parallel sides of a tank.
Tank Width (W) means the effective width over which the hood must
pull air to operate (for example, where the hood face is set back from the edge of the tank, this set back must be added in measuring tank width). The surface area of tanks can frequently be reduced and better control obtained (particularly on conveyorized systems) by using covers extending from the upper edges of the slots toward the center of the tank.
| Required minimum control velocity, f.p.m. (from Table D-57.11) |
C.f.m. per sq. ft. to maintain required minimum velocities at following ratios (tank width (W)/ tank length (L)(1),(2) |
||||
| 0.0-0.09 | 0.1-0.24 | 0.25-0.49 | 0.5-0.99 | 1.0-2.0 | |
| Hood along one side or two parallel sides of tank when one hood is against a wall or baffle(2). Also for a manifold along tank centerline(3). |
|||||
| 50 | 50 | 60 | 75 | 90 | 100 |
| 75 | 75 | 90 | 110 | 130 | 150 |
| 100 | 100 | 125 | 150 | 175 | 200 |
| 150 | 150 | 190 | 225 | 260 | 300 |
| Hood along one side or two parallel sides of free standing tank not against wall or baffle. |
|||||
| 50 | 75 | 90 | 100 | 110 | 125 |
| 75 | 110 | 130 | 150 | 170 | 190 |
| 100 | 150 | 175 | 200 | 225 | 250 |
| 150 | 225 | 260 | 300 | 340 | 375 |
Footnote(1) It is not practicable to ventilate across the long
dimension of a tank whose ratio W/L exceeds 2.0.
It is undesirable to do so when W/L exceeds 1.0. For circular tanks
with lateral exhaust along up to 1/2 the circumference, use W/L=1.0; for over one-half the circumference use W/L=0.5.
Footnote(2) Baffle is a vertical plate the same length as the tank,
and with the top of the plate as high as the tank is wide. If the exhaust hood is on the side of a tank against a building wall or close to it, it is perfectly baffled.
Footnote(3) Use W/2 as tank width in computing when manifold is along centerline, or when hoods are used on two parallel sides of a tank.
Tank Width (W) means the effective width over which the hood must
pull air to operate (for example, where the hood face is set back from the edge of the tank, this set back must be added in measuring tank width). The surface area of tanks can frequently be reduced and better control obtained (particularly on conveyorized systems) by using covers extending from the upper edges of the slots toward the center of the tank.
The vertical height of the receiving exhaust hood, including any baffle, shall not be less than one-quarter the width of the tank.
The supply airstream shall not be allowed to impinge on obstructions between it and the exhaust slot in such a manner as to significantly interfere with the performance of the exhaust hood.
Since most failure of push-pull systems result from excessive supply air volumes and pressures, methods of measuring and adjusting the supply air shall be provided. When satisfactory control has been achieved, the adjustable features of the hood shall be fixed so that they will not be altered.